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Chemistry Paper 2,Nov/Dec 2007  
Questions:   1 2 3 4 5 6 7 8   Main
General Comments
Weakness/Remedies
Strength
















































































Question 3

(a) (i)  Define each of the following terms:

  1. mole;
  2. concentration.
(ii) Consider the following equation:
2Mg(s) + O2(g) →  2MgO(s) ;
Calculate the mass of magnesium oxide that would be produced by one mole of magnesium
                        [  Mg = 24,  O = 16]    [7 marks]

(b) (i) Write a balanced chemical equation for the reaction between chlorine gas and iron (II) chloride solution.

(ii) State the reaction in 3(b)(i).  Give a reason for your answer.
(iii) State what would be observed if acidified KMnO4 is added to iron (II) chloride solution.   [7 marks]

(c) State one industrial application of each of the following methods of separation.
(i) crystallization;
(ii) filtration;
(iii) fractional distillation.   [3 marks]

(d) Name the precipitate formed when aqueous solutions of the following pairs of compounds are mixed:

(i) NaCl and Ag NO3 ;
(ii) K2SO4 and Ba Cl2;                
(iii) Pb(NO3)2 and Na2 CO3 .   [3 marks]

(e) (i) List three characteristic properties of transition metals.   
(ii) Which of the following metals belong (s) to the first transition series?
  Chromium, Lead, Manganese, Aluminium, Sodium. [5 marks]

_____________________________________________________________________________________________________
OBSERVATION

This question was attempted by most candidates and the performance was good.

In (a)(i) I and II, majority of the candidates were able to correctly define mole as the amount containing as many elementary entities as the number of atoms in 12g of
carbon– 12 and concentration as the amount of solute/substance in moles per dm3 of solution.

In(a)(ii), candidates correctly determined the mass of magnesium oxide that would be produced by 1 mole of magnesium from the given equation thus:

            2 moles of Mg  ≡   2moles of MgO
            2 moles of Mg  ≡   2 (24 + 16)g of MgO
               1 mole of Mg ≡  80   =  40g
                                           2
In (b)(i), only a few candidates could correctly write the balanced chemical equation for the reaction between chlorine gas and iron (II) chloride solution as follows:    

                 Cl2(g) + 2FeCl2(aq)      →  2FeCl3(aq)_                               
                                                                                                         
In (b)(ii), majority of the candidates stated that the reaction is oxidation instead of redox because of change in oxidation number of both Fe and Cl2 in FeCl3.

In (b)(iii), candidates correctly wrote that the colour of the acidified KMnO4 would change from purple to colourless.

In (c)(i)-(iii), most candidates wrote the general application of the separation methods instead of the required industrial application.  The expected answers from candidates were:
                        Crystallization – sugar production/pharmaceutical production
                        Filtration – water treatment plants
                        Fractional distillation – petroleum refineries.

In(d)(i) – (iii), only a few candidates correctly wrote the names of the precipitates formed while a good number of them wrote the formulae.  The required answer were
                         Silver chloride
                        Barium tetraoxosulphate (VI)
                        Lead trioxocarbonate (IV)

In (e)(i) and (ii), most candidates correctly listed three characteristic properties of transition metals from among the following:

  1. formation of coloured compounds/ions
  2. exhibition of variable oxidation states
  3. formation of complex ions
  4. exhibit paramagnetism
  5. show catalytic properties
and that only chromium and Manganese belong to the first transition series.
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