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Chemistry Paper 2 (Practical) ,May/June 2007  
Questions:       1 2 3 4 5 6   Main
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Question 6

(a) (i) Draw and label an energy profile diagram of an endothermic reaction.
Indicate on your diagram the
I.   activation energy;
II.  heat change,    H.

Explain how the rate of reaction is affected by
addition ofa:catalyst;
increase in temperature.               [8 marks]

(b) (i) Write an equation for the thermal decomposition of calcium trioxocarbonate (IV)
(ii) Determine the volume of carbon (IV) oxide measured at s.t.p. that would be produced by the thermal decomposition of 10g calcium trioxocarbonate (IV).
                        [Ca = 40; O = 16; C =12]          [5 marks]

(c )(i) Give one use of each of the following forms of carbon:
I. coal;
II. wood charcoal;
III. carbon (IV) oxide.

(ii) Write a balanced chemical equation to Show what happens when each of the following compounds, is heated strongly.
I.  Na2C03(s)
II. MgC03(s).

(d) Consider the following compounds:
CaO, CaC03 , Ca(OH) 2 ,NaOH.
Which of them is
(i) used ID the manufacture of cement;
(ii) used to detect the .presence of carbon (IV) oxide;
(iii) used to liberate carbon (IV) when dilute acid is added;
(iv) hygroscopic;
(v) deliquescent?                [5 marks]

_____________________________________________________________________________________________________
OBSERVATION

This question was not popular among the candidates but the performance was fair.

In (a) (i), some candidates correctly drew and label an energy profile diagram of an endothyrmic reaction indicating the activation energy and heat change,    H.

However, a few of them wrongly drew the energy profile diagram of an exothermic reaction and hence, lost the marks.


In (a)(ii), candidates correctly explained that addition of a catalyst increase the rate ·of a reaction by providing alternative pathway with lower activation energy and increase in temperature increases the rate of reaction because there will be more effective collisions.

In (b )(i) and (ii), candidates correctly wrote an equation for the thermal decomposition of calcium carbonate (IV) and hence, determined the volume of carbon (IV) oxide produced in the calculation as follows:

 

 

heat

 

 

 

 

(i)

CaC03(s)

CaO(8) + CO2 (g)

 

 

(ii)

Molar mass of CaC03

=

40+12+16 x3 =

100

 

10g of CaC03

=

10g =

0.1 mole

 

 

lOOgmol-1

 

 

 

1 mole of CaC03

=

1 mole of C02

 

 

OR  

 

 

 

 

 

 

 

0.1 mole of CaC03

=

0.1 mole of C02

 

 

but 1 mole

 

 

=

22.4dm3

 

 

 

0.1 mole

 

 

=

2.24dm3

 

 

In (c )(i) I - Ill, most candidates correctly gave one use each of coal, wood charcoal and carbon (IV) oxide as follows:
I. Coal - as fuel.
II Wood charcoal - for absorbing poisonous gases/as domestic fuel
Ill. Carbon (IV)oxide - in fire extinguishers.
- manufacture of washing soda by solvay process in . carbonated drinks.
In (c )(ii) I - 11, majority of the candidates correctly wrote the thermal decomposition of NaN03(s) and MgC03(s) as follows:
                          heat
I.  2NaNo3       2NaNO3(g)  +   O2(g)
                          heat
II.  MgCo3(s)         MgO(s)    +   CO(g)

In (d)(i)-(v)  candidates correctly matches the compounds as follows:

(i) CaCO3 -  cement
(ii) Ca(OH)2  -   detection of CO2
(iii) CaCO3 -  liberates CO2 with addition of acids
(iv) CaO -  hygroscopic.
(v) NaOH -    deliquescent

               
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